Abstract
Recent experiments on several oxide perovskites reveal that they undergo tilt phase transitions to higher-symmetry phases on increasing pressure and that , contrary to a general rule previously proposed for such zone-boundary transitions. We show that the negative slope of the phase boundary is a consequence of the octahedra in these perovskites being more compressible than the extra-framework cation sites. Conversely, when the octahedra are stiffer than the extra-framework cation sites, the phase transition temperatures increase with increasing pressure, .
- Received 29 April 2005
DOI:https://doi.org/10.1103/PhysRevLett.95.025503
©2005 American Physical Society