Abstract
We report the first ab initio quantum treatment of microwave driven alkali Rydberg states. We find that nonhydrogenic atomic initial states exhibit fingerprints of classically chaotic excitation, and identify the cause of their experimentally observed enhanced ionization, as compared to Rydberg states of atomic hydrogen.
- Received 18 December 2000
DOI:https://doi.org/10.1103/PhysRevLett.86.3538
©2001 American Physical Society