Stable and unstable phases of a diblock copolymer melt

M. W. Matsen and M. Schick
Phys. Rev. Lett. 72, 2660 – Published 18 April 1994
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Abstract

Using self-consistent field theory, we examine microphases of diblock copolymers and find, in addition to lamellar, hexagonal, and cubic phases, a stable gyroid phase which occurs between the lamellar and hexagonal ones. It terminates at a triple point, with a lamellar to hexagonal transition occurring in the weak-segregation limit. Other phases of experimental interest are studied, and we describe the regions in which they are most nearly stable.

  • Received 25 February 1994

DOI:https://doi.org/10.1103/PhysRevLett.72.2660

©1994 American Physical Society

Authors & Affiliations

M. W. Matsen and M. Schick

  • Department of Physics FM-15, University of Washington, Seattle, Washington 98195

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Vol. 72, Iss. 16 — 18 April 1994

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