Quantum Theory of Activated Events in Condensed Phases

Peter G. Wolynes
Phys. Rev. Lett. 47, 968 – Published 28 September 1981
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Abstract

The quantum analog of Kramers's classical theory of the rate of activated events is presented. By means of a path-integral approach, the correlation function expression for the rate of barrier crossing by a quantum mechanical particle coupled to a heat bath is evaluated for finite temperatures. Tunneling effects are dramatically diminished by the frictional influence of the heat bath.

  • Received 2 March 1981

DOI:https://doi.org/10.1103/PhysRevLett.47.968

©1981 American Physical Society

Authors & Affiliations

Peter G. Wolynes

  • School of Chemical Sciences, University of Illinois at Urbana-Champaign, Urbana, Illinois 61801

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Issue

Vol. 47, Iss. 13 — 28 September 1981

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