Abstract
We present a novel method for probing the alignment of the molecular axis of an ultracold, nonpolar dimer. These results are obtained using diatomic molecules in the vibrational ground state of the lowest triplet potential trapped in a 3D optical lattice. We measure the molecular polarizabilities, which are directly linked to the alignment, along each of the , , and directions of the lab coordinate system. By preparing the molecules in various, precisely defined rotational quantum states we can control the degree of alignment of the molecular axis with high precision over a large range. Furthermore, we derive the dynamical polarizabilities for a laser wavelength of 1064.5 nm parallel and orthogonal to the molecular axis of the dimer, and , respectively. Our findings highlight that the depth of an optical lattice strongly depends on the rotational state of the molecule, which has to be considered in collision experiments. The present work paves the way for reaction studies between aligned molecules in the ultracold temperature regime.
- Received 4 April 2014
DOI:https://doi.org/10.1103/PhysRevLett.113.233004
© 2014 American Physical Society
Synopsis
Making Molecules Stand to Attention
Published 3 December 2014
Cold molecules trapped in an optical lattice can be aligned by controlling their rotational quantum state.
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