Abstract
Oxygen vacancies created in anatase by UV photons (80–130 eV) provide an effective electron-doping mechanism and induce a hitherto unobserved dispersive metallic state. Angle resolved photoemission reveals that the quasiparticles are large polarons. These results indicate that anatase can be tuned from an insulator to a polaron gas to a weakly correlated metal as a function of doping and clarify the nature of conductivity in this material.
- Received 26 February 2013
DOI:https://doi.org/10.1103/PhysRevLett.110.196403
© 2013 American Physical Society