Abstract
We investigate the interaction of single molecule magnets (SMMs) with ferromagnetic Ni substrates. Using element-resolved x-ray magnetic circular dichroism, we show that couples antiferromagnetically to Ni films through ligand-mediated superexchange. This coupling is strongly anisotropic and can be manipulated by doping the interface with electron acceptor or donor atoms. We observe that the relative orientation of the substrate and molecule anisotropy axes critically affects the SMM magnetic behavior. complexes deposited on perpendicularly magnetized Ni films exhibit enhanced magnetic remanence compared to SMMs in the bulk. Contrary to paramagnetic molecules pinned to a ferromagnetic support layer, we find that can be magnetized parallel or antiparallel to the substrate, opening the possibility to exploit SMMs in spin valve devices.
- Received 12 May 2011
DOI:https://doi.org/10.1103/PhysRevLett.107.177205
© 2011 American Physical Society