Onset of phase separation in the double perovskite oxide La2MnNiO6

Steven R. Spurgeon, Peter V. Sushko, Arun Devaraj, Yingge Du, Timothy Droubay, and Scott A. Chambers
Phys. Rev. B 97, 134110 – Published 13 April 2018
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Abstract

Identification of kinetic and thermodynamic factors that control crystal nucleation and growth represents a central challenge in materials synthesis. Here we report that apparently defect-free growth of La2MnNiO6 (LMNO) thin films supported on SrTiO3 (STO) proceeds up to 1–5 nm, after which it is disrupted by precipitation of NiO phases. Local geometric phase analysis and ensemble-averaged x-ray reciprocal space mapping show no change in the film strain away from the interface, indicating that mechanisms other than strain relaxation induce the formation of the NiO phases. Ab initio simulations suggest that the electrostatic potential build-up associated with the polarity mismatch at the film-substrate interface promotes the formation of oxygen vacancies with increasing thickness. In turn, oxygen deficiency promotes the formation of Ni-rich regions, which points to the built-in potential as an additional factor that contributes to the NiO precipitation mechanisms. These results suggest that the precipitate-free region could be extended further by either incorporating dopants that suppress the built-in potential or by increasing the oxygen fugacity in order to suppress the formation of oxygen vacancies.

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  • Received 24 October 2017
  • Revised 2 February 2018

DOI:https://doi.org/10.1103/PhysRevB.97.134110

©2018 American Physical Society

Physics Subject Headings (PhySH)

Condensed Matter, Materials & Applied Physics

Authors & Affiliations

Steven R. Spurgeon*, Peter V. Sushko, Arun Devaraj, Yingge Du, Timothy Droubay, and Scott A. Chambers

  • Physical and Computational Sciences Directorate, Pacific Northwest National Laboratory, Richland, Washington 99352, USA

  • *steven.spurgeon@pnnl.gov
  • sa.chambers@pnnl.gov

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Issue

Vol. 97, Iss. 13 — 1 April 2018

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