Abstract
We have investigated change in the electronic structures of atomically controlled (LSMO) thin films as a function of hole-doping levels in terms of in vacuo photoemission spectroscopy (PES) and x-ray absorption spectroscopy (XAS) measurements. The in vacuo PES measurements on a well-ordered surface of high-quality epitaxial LSMO thin films enable us to reveal their intrinsic electronic structures, especially the structure near the Fermi level . We found that overall the features of the valence band as well as the core levels monotonically shifted toward lower binding energy as was increased, indicating the systematic chemical-potential shift of LSMO thin films with hole doping. The peak nearest to due to the orbital is also found to move toward , while the peak intensity decreases with increasing . The loss of spectral weight with in the occupied density of states was compensated by the simultaneous increment of the shoulder structure in O XAS spectra, suggesting the existence of a pseudogap, that is, a lowering in spectral weight at , for all metallic compositions. These results indicate that the simple rigid-band model does not describe the electronic structure near of LSMO, and that the spectral weight transfer from below to above across the gap dominates the spectral changes with in LSMO thin films.
1 More- Received 11 June 2004
DOI:https://doi.org/10.1103/PhysRevB.71.155420
©2005 American Physical Society