Abstract
Single crystals of the entire series of to Lu, and Y) pyrochlore compounds were irradiated by 1-MeV ions at temperatures from 293 to 1073 K, and the microstructure evolution, as a function of increasing radiation fluence, was characterized using in situ transmission electron microscopy (TEM). The critical amorphization temperature, generally increases from ∼480 to ∼1120 K with increasing A-site cation size (e.g., 0.977 Å for to 1.079 Å for An abnormally high susceptibility to ion beam damage was found for (with the highest of ∼1120 K). Factors influencing the response of titanate pyrochlores to ion irradiation-induced amorphization are discussed in terms of cation radius ratio, defect formation, and the tendency to undergo an order-disorder transition to the defect-fluorite structure. The resistance of the pyrochlore structure to ion beam-induced amorphization is not only affected by the relative sizes of the A- and B-site cations, but also the cation electronic configuration and the structural disorder. Pyrochlore compositions that have larger structural deviations from the ideal fluorite structure, as evidenced by the smaller oxygen positional parameter, x, are more sensitive to ion beam-induced amorphization.
- Received 12 November 2002
DOI:https://doi.org/10.1103/PhysRevB.68.134107
©2003 American Physical Society