Ground-state properties of nanographite systems with zigzag edges

Toshiya Hikihara, Xiao Hu, Hsiu-Hau Lin, and Chung-Yu Mou
Phys. Rev. B 68, 035432 – Published 30 July 2003
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Abstract

A π-electron network in nanographite systems with zigzag edges exhibits strongly localized edge states, which are expected to have peculiar properties. We study effects of electron-electron interactions on ground-state properties of zigzag nanographite ribbons and open-ended zigzag nanotubes by means of the weak-coupling renormalization group and the density-matrix renormalization-group method. It is shown that the ground state is a spin-singlet Mott insulator with finite charge and spin gaps. We also find that the edge states are robust against the electronic correlations, resulting in edge-effective spins that can flip almost freely. The schematic picture for the low-energy physics of the systems is discussed.

  • Received 10 March 2003

DOI:https://doi.org/10.1103/PhysRevB.68.035432

©2003 American Physical Society

Authors & Affiliations

Toshiya Hikihara1,*, Xiao Hu1, Hsiu-Hau Lin2,3, and Chung-Yu Mou2

  • 1Computational Materials Science Center, National Institute for Materials Science, Tsukuba, Ibaragi 305-0047, Japan
  • 2Department of Physics, National Tsing-Hua University, Hsinchu 300, Taiwan
  • 3Physics Division, National Center for Theoretical Science, Hsinchu 300, Taiwan

  • *Present address: Condensed Matter Theory Laboratory, Institute of Physical and Chemical Research (RIKEN), Wako 351-0198, Japan. Email address: hikihara@riken.go.jp

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Vol. 68, Iss. 3 — 15 July 2003

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