Abstract
Effects of chemical and external pressures have been investigated on the two types of charge-ordering (CO) systems of perovskite manganites with the use of single-crystal specimens: One is with moderate CO instability occurring only near x=1/2 and the other is with stronger CO instability extending over a wide x region 0.3⩽x⩽0.7. We have partially substituted the Nd ions of with larger La ions or applied external pressure on them with the aim of destabilizing the CO state via an increase of the 3d-electron hopping interaction. An electronic phase diagram relevant to the CO transition was derived for ( by such a control of the one-electron bandwidth (W). With an increase of W, the enhanced ferromagnetic double-exchange interaction increases the Curie temperature () and suppresses the charge-ordered state with a concomitant antiferromagnetic charge-exchange-type spin ordering (AF-CE). In a narrow window of z (0.4⩽z⩽0.6) or in the pressurized state for z=0.4, another type of antiferromagnetic (perhaps the A type) phase replaces the AF-CE state. Application of external pressure and resultant enhanced carrier itineracy suppresses the CO transitions also for . For the x=0.30 crystal, application of pressure induces a metallic phase from the low-temperature side in the charge-ordered insulating phase. The pressure-temperature phase diagrams relating to the CO transition or the concurrent insulator-to-metal transition were shown to scale well with the magnetic-field–temperature phase diagrams.
DOI:https://doi.org/10.1103/PhysRevB.55.7549
©1997 American Physical Society