Abstract
The electronic structure of the planes and chains in single-domain crystals of has been investigated as a function of oxygen concentration (6≤x≤7) using polarization-dependent x-ray-absorption spectroscopy of the O 1s and Cu 2p core levels. The polarization-dependent observation of unoccupied states with O and with Cu orbital character parallel to the a, b, and c axes of the crystals allows the determination of the number of hole states in Cu 3- and O 2y orbitals in the planes as well as in Cu 3- and O 2z orbitals in the chains. States with Cu 3- orbital character contribute less than 10% to the total number of states near the Fermi level. The number of holes in the planes and in the chains is found to be correlated with the superconducting transition temperature.
- Received 21 November 1994
DOI:https://doi.org/10.1103/PhysRevB.51.8529
©1995 American Physical Society