Abstract
We interpret the giant infrared resonances observed in (A=K, Rb) by Fu et al. as being due to a classical charged-phonon effect in which the molecular vibration modes of acquire electronic oscilator strength via couplng to virtual → electronic transitions. For the compounds (x=3, 4, and 6), we predict, for weak electron–molecular-vibration coupling, that the softenings of the modes are proportional to x, but that the integrated oscillator strengths of their absorption bands are proportional to the square of x.
- Received 16 December 1991
DOI:https://doi.org/10.1103/PhysRevB.45.10173
©1992 American Physical Society