Further investigation of g factors for the lead monofluoride ground state

L. V. Skripnikov, A. N. Petrov, A. V. Titov, R. J. Mawhorter, A. L. Baum, T. J. Sears, and J.-U. Grabow
Phys. Rev. A 92, 032508 – Published 15 September 2015

Abstract

We report the results of our theoretical study and analysis of earlier experimental data for the g-factor tensor components of the ground 2Π1/2 state of the free PbF radical. The values were obtained both within the relativistic coupled-cluster method combined with the generalized relativistic effective core potential approach and with our fit of the experimental data from [R. J. Mawhorter, B. S. Murphy, A. L. Baum, T. J. Sears, T. Yang, P. M. Rupasinghe, C. P. McRaven, N. E. Shafer-Ray, L. D. Alphei, and J.-U. Grabow, Phys. Rev. A 84, 022508 (2011); A. L. Baum, B.A. thesis, Pomona College, 2011]. The obtained results agree very well with each other but contradict the previous fit performed in the cited works. Our final prediction for g factors is G=0.081(5),G=0.27(1).

  • Received 1 May 2015

DOI:https://doi.org/10.1103/PhysRevA.92.032508

©2015 American Physical Society

Authors & Affiliations

L. V. Skripnikov1,2,*, A. N. Petrov1,2,†, A. V. Titov1,2,‡, R. J. Mawhorter3,4, A. L. Baum3, T. J. Sears5, and J.-U. Grabow4

  • 1National Research Centre “Kurchatov Institute” B. P. Konstantinov Petersburg Nuclear Physics Institute, Gatchina, Leningrad District, 188300 Russia
  • 2Saint-Petersburg University, Saint Petersburg State University, SPbSU, SPbU, 7/9 Universitetskaya nab., Saint Petersburg, 199034 Russia
  • 3Department of Physics and Astronomy, Pomona College, Claremont, California 91711-6359, USA
  • 4Gottfried-Wilhelm-Leibniz-Universität, Institut für Physikalische Chemie and Elektrochemie, Lehrgebiet A, Hannover, D-30167 Germany
  • 5Chemistry Department, Brookhaven National Laboratory, Upton, New York 11973-5000, USA

  • *leonidos239@gmail.com
  • alexsandernp@gmail.com
  • http://www.qchem.pnpi.spb.ru

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Vol. 92, Iss. 3 — September 2015

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