Relativistic many-body calculation of energies, transition rates, lifetimes, and multipole polarizabilities in Cs-like La iii

U. I. Safronova and M. S. Safronova
Phys. Rev. A 89, 052515 – Published 20 May 2014

Abstract

Excitation energies of the [Xe]nd (n=59), [Xe]ns (n=610), [Xe]np (n=69), [Xe]nf (n=48), and [Xe]ng (n=58) states in La iii, where [Xe] = 1s22s22p63s23p63d104s24p64d105s25p6, are evaluated. Electric dipole matrix elements for the allowed transitions between the low-lying [Xe]nd, [Xe]ns, [Xe]np, [Xe]nf, and [Xe]ng states in the La iii ion are calculated using the high-precision relativistic all-order method where all single, double, and partial triple excitations of the Dirac-Fock wave functions are included to all orders of perturbation theory. Recommended values are provided for a large number of electric dipole matrix elements, oscillator strengths, transition rates, and lifetimes. Scalar and tensor polarizabilities of the states listed above are evaluated. The uncertainties of the recommended values are estimated. Electric quadrupole and magnetic dipole matrix elements are calculated to determine lifetimes of the 5d5/2 and 6s metastable levels. The ground-state E1, E2, and E3 static polarizabilities are calculated. This work provides recommended values critically evaluated for their accuracy for a number of La iii atomic properties for use in planning and analysis of various experiments as well as theoretical modeling.

  • Received 31 March 2014

DOI:https://doi.org/10.1103/PhysRevA.89.052515

©2014 American Physical Society

Authors & Affiliations

U. I. Safronova1,2 and M. S. Safronova3,4

  • 1Physics Department, University of Nevada, Reno, Nevada 89557, USA
  • 2Department of Physics, University of Notre Dame, Notre Dame, Indiana 46556, USA
  • 3Department of Physics and Astronomy, 217 Sharp Laboratory, University of Delaware, Newark, Delaware 19716, USA
  • 4Joint Quantum Institute, National Institute of Standards and Technology and University of Maryland, College Park, Maryland 20742, USA

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Issue

Vol. 89, Iss. 5 — May 2014

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