Abstract
The multiconfiguration time-dependent Hartree approach is applied to study the electron-nuclear correlation in the dynamics of molecules subject to strong external laser fields, using the example of a model hydrogen molecular ion. The ground state of the system is well described by as few as two single-particle functions per degree of freedom. A significantly larger but moderate number of configurations is required to predict laser-induced fragmentation probabilities and high-order harmonic generation spectra accurately, showing that the correlation between electronic and nuclear degree of freedom is strongly increased by the presence of the laser field.
- Received 2 April 2010
DOI:https://doi.org/10.1103/PhysRevA.81.063421
©2010 American Physical Society