Abstract
We report ab initio relativistic correlation calculations of potential curves for ten low-lying electronic states, the effective electric field on the electron, and hyperfine constants for the state of a cation of the heavy transition metal fluoride , which it is suggested can be used in experiments to search for the electric dipole moment of the electron. It is shown that has a deeply bound ground state; its dissociation energy is . The state is obtained as the relatively long-lived first excited state lying about higher. The calculated effective electric field acting on an electron in this state is .
- Received 23 January 2007
DOI:https://doi.org/10.1103/PhysRevA.76.030501
©2007 American Physical Society