Abstract
The collision-induced, rototranslational absorption spectrum of compressed methane gas is computed, based purely on the reliably known, leading multipole-induced dipole components of molecular pairs. In contrast to previous work of the kind no ad hoc empirical corrections of unknown exchange force-induced dipole components are attempted. Not surprisingly, the calculated spectra show a sizeable absorption defect at virtually all frequencies, when compared to existing laboratory measurements. The defect suggests the presence of dipole-induction mechanisms in addition to those due to the leading multipole-induced dipole terms. The excess absorption, the differences between measured and calculated spectra, resembles in certain ways the excess absorption spectra seen at the same frequencies in methane- gas mixtures, where stands for helium, hydrogen, or nitrogen, respectively [Buser and Frommhold, J. Chem. Phys. 122, 024301 (2005)]. To a large extent, the excess absorption seems to be related to collisional distortions of the tetrahedral frame of the unperturbed molecule.
- Received 14 July 2005
DOI:https://doi.org/10.1103/PhysRevA.72.042715
©2005 American Physical Society