Energies and polarizabilities of the hydrogen molecular ions

Zong-Chao Yan, Jun-Yi Zhang, and Yue Li
Phys. Rev. A 67, 062504 – Published 18 June 2003
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Abstract

The nonrelativistic energies of the hydrogen molecular ions H2+, D2+, T2+, HD+, HT+, and DT+ are evaluated for the ground and the first-excited P states, using variational wave functions in Hylleraas coordinates. The dipole polarizabilities of the ground states of the ions are determined precisely. Our results for the dipole polarizabilities represent the most accurate calculations reported so far. For H2+, for example, the dipole polarizability is 3.16872580267(1)a03, with the uncertainty of three parts in 1012.

  • Received 19 February 2003

DOI:https://doi.org/10.1103/PhysRevA.67.062504

©2003 American Physical Society

Authors & Affiliations

Zong-Chao Yan, Jun-Yi Zhang, and Yue Li

  • Department of Physics, University of New Brunswick, P.O. Box 4400, Fredericton, New Brunswick, Canada E3B 5A3

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Vol. 67, Iss. 6 — June 2003

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