Abstract
We present molecular-orbital x-ray spectra from collision systems with highly charged projectiles calculated with a time-dependent coupled channel method using relativistic molecular Dirac-Fock-Slater wave functions and full radial and rotational couplings. The spectra of the system are investigated with respect to the dynamics and the number of electrons in the system. Two basis sets have been employed in the calculation, one which belongs to the ground-state configuration and the other to the transition-state configuration on the incoming part of the trajectory respectively. Very good agreement with the experimental results is found by using the transition state basis set.
- Received 19 April 1999
DOI:https://doi.org/10.1103/PhysRevA.63.022503
©2001 American Physical Society