Scaling concepts for the dynamics of viscous liquids near an ideal glassy state

T. R. Kirkpatrick, D. Thirumalai, and P. G. Wolynes
Phys. Rev. A 40, 1045 – Published 1 July 1989
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Abstract

Motivated by recent mean-field theories of the structural glass transition and of the Potts glass model we formulate a scaling and droplet picture of an assumed ideal structural glass transition. The phase transition is a random first-order phase transition where the supercooled-liquid phase is composed of glassy clusters separated by interfaces or domain walls. Because of entropic driving forces the glassy clusters are continually being created and destroyed. As the ideal transition temperature is approached the entropic driving force vanishes and the size of the glassy clusters diverges with an exponent of ν=2/d. All long-time dynamical processes are activated and the Vogel-Fulcher law is obtained for the liquid-state relaxation time.

  • Received 22 February 1989

DOI:https://doi.org/10.1103/PhysRevA.40.1045

©1989 American Physical Society

Authors & Affiliations

T. R. Kirkpatrick and D. Thirumalai

  • Institute for Physical Science and Technology, University of Maryland, College Park, Maryland 20742

P. G. Wolynes

  • Noyes Laboratory, University of Illinois at Urbana–Champaign, Urbana, Illinois 61801

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Vol. 40, Iss. 2 — July 1989

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