Abstract
Ab initio calculations are presented for the vibrational branching ratios in three-photon resonant four-photon ionization of via the state. Energy and internuclear distance dependences of the boundfree electronic transition matrix element are explicitly included to estimate deviations from the Franck-Condon approximation. While our calculated branching ratios confirm certain important trends seen experimentally, some differences remain.
- Received 4 September 1984
DOI:https://doi.org/10.1103/PhysRevA.30.3332
©1984 American Physical Society