Abstract
The multichannel -matrix technique is used to solve the pseudostate close-coupling equations for photodetachment using only basis functions and standard configuration-interaction techniques. The problem of linear dependence which arises when the same basis is used to expand both the target and free electrons is discussed and exactly solved using a matrix partitioning. Results for total and partial photodetachment cross sections are given from threshold to 70-eV photon energy (1664 to 18 nm) with emphasis on the single-photon two-electron ejection cross section, and the shape resonance just above the hydrogenic threshold.
- Received 3 August 1976
DOI:https://doi.org/10.1103/PhysRevA.14.2159
©1976 American Physical Society