Abstract
We have used the Cryogenic Storage Ring (CSR) at the Max Planck Institute for Nuclear Physics to study long-lived metastable states of the silicon anion. A beam of 58 keV kinetic energy was stored in the ultrahigh cryogenic vacuum of the CSR, employing only electrostatic deflection elements. We used laser systems at various wavelengths to infer information on the decay of the metastable anionic states by selective photodetachment. Our results give evidence of an excited anionic state for which we determine the extremely long lower lifetime limit of 5.7 h at 90% confidence level, consistent with theoretical predictions for the term. Furthermore, we find an average lifetime of s for the weakly bound states, employing coincidence counting with a pulsed nanosecond laser at 2.45 . Using a laser depletion technique, we produce a pure ground term beam, and we quantify the fraction of ions in metastable states in our initial ion sample. We combine our experimental efforts with state-of-the-art multiconfiguration Dirac-Hartree-Fock calculations for the radiative lifetimes of all metastable levels of . We find these calculations to be in excellent agreement with our measurements and to improve previous efforts considerably.
1 More- Received 17 May 2021
- Accepted 9 August 2021
DOI:https://doi.org/10.1103/PhysRevA.104.032811
Published by the American Physical Society under the terms of the Creative Commons Attribution 4.0 International license. Further distribution of this work must maintain attribution to the author(s) and the published article's title, journal citation, and DOI. Open access publication funded by the Max Planck Society.
Published by the American Physical Society