Abstract
We reconsider the calculation of rovibrational transition frequencies in hydrogen molecular ions. Some previously neglected contributions, such as the deuteron polarizability, are included into consideration in comparison with our previous work. In particular, one-loop and two-loop QED corrections at and orders are recalculated in the framework of the adiabatic approximation, with systematic inclusion of corrections associated with vibrational motion. Improved theoretical transition frequencies are obtained and found to be in very good agreement with recent high-precision spectroscopy experiments in . New values for the and mass ratios are determined.
- Received 30 July 2021
- Accepted 26 August 2021
DOI:https://doi.org/10.1103/PhysRevA.104.032806
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