Lower Bounds for the Helmholtz Function

Sidney Golden
Phys. Rev. 137, B1127 – Published 22 February 1965
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Abstract

A mathematical theorem is established for traces of products of bounded Hermitian and definite operators, a and b: Tr(ab)2p+1<~Tr(a2b2)2p for p a non-negative integer. This theorem is applied to the equilibrium partition function by exploiting an infinite-product representation of the exponential function of the sum of two operators. As a result, a set of inequalities is established which yields a set of upper bounds for the partition function. This result is invariant to the particle statistics of the system. A general argument yields the result that the classical Helmholtz free-energy function serves as a lower bound to the corresponding quantum result.

  • Received 1 October 1964

DOI:https://doi.org/10.1103/PhysRev.137.B1127

©1965 American Physical Society

Authors & Affiliations

Sidney Golden

  • Department of Chemistry, Brandeis University, Waltham, Massachusetts

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Issue

Vol. 137, Iss. 4B — February 1965

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