Abstract
The photodissociation of superexcited to and atoms, with subsequent autoionization to at 22.36 eV photon energy, was studied by a new method: angle resolved photoelectron-photoion coincidence spectroscopy. A position-sensitive detector was used to measure the three components of the fragment ion velocity. When the excited atom autoionizes it emits an electron preferentially along the photodissociation axis, with a 12% greater probability to be emitted away from the recessing ground-state atom than towards the latter, pointing to possible intramolecular scattering of the electron on its way out.
- Received 21 July 1997
DOI:https://doi.org/10.1103/PhysRevLett.79.4554
©1997 American Physical Society