Hyperfine structure intervals and absolute frequency measurement in the 2p43s2PJ2p43p2DJ fine-structure multiplet of atomic fluorine by diode laser spectroscopy

D. A. Tate and D. N. Aturaliye
Phys. Rev. A 56, 1844 – Published 1 September 1997
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Abstract

We have measured the hyperfine structure splittings of the three components of the 2p43s2PJ2p43p2DJ multiplet in atomic fluorine using both Doppler-free saturated absorption spectroscopy with an external cavity diode laser and Doppler-limited absorption spectroscopy with a noncavity diode laser. Specifically, we have obtained spectra of the J=1/2J=3/2 transition 780 nm, the J=3/2J=5/2 transition at 775 nm, and the J=3/2J=3/2 transition at 761 nm. The fluorine atoms were generated from a 10% mix of F2 in He using a 2.45-GHz microwave generator and cavity pressures of approximately 0.5 torr. We report here values for hyperfine splittings and constants for the upper and lower states of these transitions. In addition, the absolute frequency of one of the hyperfine components of the J=1/2J=3/2 transition at 780 nm was measured using a recent absolute frequency measurement of the D2 transition in Rb.

  • Received 29 January 1997

DOI:https://doi.org/10.1103/PhysRevA.56.1844

©1997 American Physical Society

Authors & Affiliations

D. A. Tate and D. N. Aturaliye

  • Department of Physics and Astronomy, Colby College, Waterville, Maine 04901

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Vol. 56, Iss. 3 — September 1997

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