Self-assembly and tunable mechanics of reconfigurable colloidal crystals

Kevin L. Kohlstedt and Sharon C. Glotzer
Phys. Rev. E 87, 032305 – Published 13 March 2013
PDFHTMLExport Citation

Abstract

We investigate the self-assembly of crystals from reconfigurable colloidal building blocks. The building blocks possess the unique ability, inspired by recent experiments, to continuously alter their shape before, during, and after assembly. Using molecular simulations, we report the assembly of a reconfigurable degenerate crystal containing a fractionally filled kagome sublattice. We show that this degenerate crystal differs from, and assembles more easily than, its counterpart known for rigid dimers. We further report that the reconfigurable crystal has unique mechanical properties under shear strain compared to a crystal comprised of rigid building blocks. We find that even a small amount of reconfigurability in an assembly of otherwise rigid building blocks can greatly affect mechanical properties.

  • Figure
  • Figure
  • Figure
  • Figure
  • Received 18 April 2012

DOI:https://doi.org/10.1103/PhysRevE.87.032305

©2013 American Physical Society

Authors & Affiliations

Kevin L. Kohlstedt* and Sharon C. Glotzer

  • Departments of Chemical Engineering and Materials Science & Engineering, University of Michigan, Ann Arbor, Michigan 48109, USA

  • *Current address: Department of Chemistry, Northwestern University, Evanston, IL 60208.
  • Corresponding author: sglotzer@umich.edu

Article Text (Subscription Required)

Click to Expand

Supplemental Material (Subscription Required)

Click to Expand

References (Subscription Required)

Click to Expand
Issue

Vol. 87, Iss. 3 — March 2013

Reuse & Permissions
Access Options
Author publication services for translation and copyediting assistance advertisement

Authorization Required


×
×

Images

×

Sign up to receive regular email alerts from Physical Review E

Log In

Cancel
×

Search


Article Lookup

Paste a citation or DOI

Enter a citation
×