Abstract
The effects of Sn lone pairs in the different phases of Sn sulphides are investigated with photoreflectance, hard x-ray photoemission spectroscopy (HAXPES), and density functional theory. Due to the photon energy-dependence of the photoionization cross sections, at high photon energy, the Sn orbital photoemission has increased intensity relative to that from other orbitals. This enables the Sn state contribution at the top of the valence band in the different Sn-sulphides, SnS, , and , to be clearly identified. SnS and contain Sn(II) cations and the corresponding Sn lone pairs are at the valence band maximum (VBM), leading to –1.3 eV band gaps and relatively high VBM on an absolute energy scale. In contrast, only contains Sn(IV) cations, no filled lone pairs, and therefore has a eV room-temperature band gap and much lower VBM compared with SnS and . The direct band gaps of these materials at 20 K are found using photoreflectance to be 1.36, 1.08, and 2.47 eV for SnS, , and , respectively, which further highlights the effect of having the lone-pair states at the VBM. As well as elucidating the role of the Sn lone pairs in determining the band gaps and band alignments of the family of Sn-sulphide compounds, this also highlights how HAXPES is an ideal method for probing the lone-pair contribution to the density of states of the emerging class of materials with configuration.
- Received 28 February 2020
- Revised 5 May 2020
- Accepted 2 June 2020
DOI:https://doi.org/10.1103/PhysRevMaterials.4.074602
Published by the American Physical Society under the terms of the Creative Commons Attribution 4.0 International license. Further distribution of this work must maintain attribution to the author(s) and the published article's title, journal citation, and DOI.
Published by the American Physical Society