Abstract
We report conduction measurements on the clean, free surface of transparent insulating single crystals in high vacuum. We find that the insulating crystals exhibit surface conductance that is dependent on the spontaneous polarization, whereas no conduction perpendicular to the surface is observed. The surface conduction shows semimetallic temperature dependence and persists down to at least 100 K. The observations suggest a two-dimensional electron on a clean, free ferroelectric surface that may be regarded as a ferroelectric metal. The results have important implications for understandings of the fundamental properties of ferroelectrics, the size effect, and ferroelectric devices.
- Received 10 July 2000
DOI:https://doi.org/10.1103/PhysRevLett.86.332
©2001 American Physical Society