Abstract
Size-selected stored metal cluster ions, , have been heated by photoexcitation ( to 229 nm) to well-defined excitation energies corresponding to temperatures between 1000 and 2100 K. A millisecond pump-probe photodissociation technique was applied to measure the time-resolved radiative cooling. The observed decay rates are directly related to the radiative energy loss and are explained quantitatively by the competing processes of photoemission and atom evaporation.
- Received 22 March 1999
DOI:https://doi.org/10.1103/PhysRevLett.83.3816
©1999 American Physical Society