Are Vicinal Metal Surfaces Stable?

J. W. M. Frenken and P. Stoltze
Phys. Rev. Lett. 82, 3500 – Published 26 April 1999
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Abstract

We use effective medium theory to demonstrate that the energies of many metal surfaces are lowered when these surfaces are replaced by facets with lower-index orientations. This implies that the low-temperature equilibrium shapes of many metal crystals should be heavily faceted. The predicted instability of vicinal metal surfaces is at variance with the almost generally observed stability of these surfaces. We argue that the unstable orientations undergo a defaceting transition at relatively low temperatures, driven by the high vibrational entropy of steps.

  • Received 13 November 1998

DOI:https://doi.org/10.1103/PhysRevLett.82.3500

©1999 American Physical Society

Authors & Affiliations

J. W. M. Frenken

  • Kamerlingh Onnes Laboratory, Leiden University, P.O. Box 9504, 2300 RA Leiden, The Netherlands

P. Stoltze

  • Center for Atomic-scale Materials Physics, Department of Physics, Technical University of Denmark, DK-2800 Lyngby, Denmark

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Vol. 82, Iss. 17 — 26 April 1999

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