X-Ray Fluorescence Correlation Spectroscopy: A Method for Studying Particle Dynamics in Condensed Matter

Jin Wang, Ajay K. Sood, Parlapalli V. Satyam, Yiping Feng, Xiao-zhong Wu, Zhonghou Cai, Wenbing Yun, and Sunil K. Sinha
Phys. Rev. Lett. 80, 1110 – Published 2 February 1998
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Abstract

We have demonstrated that x-ray fluorescence correlation spectroscopy, in conjunction with microfocused synchrotron x-ray beams, can be used for elucidating particle dynamics. The dynamics of gold and ferromagnetic colloidal particles and aggregates undergoing both diffusion and sedimentation in water has been studied by measuring the time autocorrelation of the x-ray fluorescence intensity from a small illuminated volume. The dynamical parameters obtained are in excellent agreement with theoretical estimates and other measurements. Potential applications of the technique are discussed.

  • Received 1 October 1997

DOI:https://doi.org/10.1103/PhysRevLett.80.1110

©1998 American Physical Society

Authors & Affiliations

Jin Wang1, Ajay K. Sood1,*, Parlapalli V. Satyam1, Yiping Feng1, Xiao-zhong Wu2,3, Zhonghou Cai1, Wenbing Yun1, and Sunil K. Sinha1

  • 1Experimental Facilities Division, Argonne National Laboratory, Argonne, Illinois 60439
  • 2Department of Physics, Northern Illinois University, Dekalb, Illinois 60115
  • 3and Materials Science Division, Argonne National Laboratory, Argonne, Illinois 60439

  • *On leave from Department of Physics, Indian Institute of Science, Bangalore 560012, India.

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Vol. 80, Iss. 5 — 2 February 1998

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