Current-Dependent Exchange-Correlation Potential for Dynamical Linear Response Theory

G. Vignale and Walter Kohn
Phys. Rev. Lett. 77, 2037 – Published 2 September 1996
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Abstract

The frequency-dependent exchange-correlation potential, which appears in the usual Kohn-Sham formulation of a time-dependent linear response problem, is a strongly nonlocal functional of the density, so that a consistent local density approximation generally does not exist. This problem can be avoided by choosing the current density as the basic variable in a generalized Kohn-Sham theory. This theory admits a local approximation which, for fixed frequency, is exact in the limit of slowly varying densities and perturbing potentials.

  • Received 26 April 1996

DOI:https://doi.org/10.1103/PhysRevLett.77.2037

©1996 American Physical Society

Authors & Affiliations

G. Vignale

  • Department of Physics, University of Missouri, Columbia, Missouri 65211

Walter Kohn

  • Department of Physics, University of California, Santa Barbara, California 93106-4030

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Vol. 77, Iss. 10 — 2 September 1996

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