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Evidence for the Tunneling Site on Transition-Metal Oxides: TiO2(110)

Ulrike Diebold, J. F. Anderson, Kwok-On Ng, and David Vanderbilt
Phys. Rev. Lett. 77, 1322 – Published 12 August 1996
An article within the collection: Scanning Probe Microscopy: From Sublime to Ubiquitous
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Abstract

We present atomically resolved scanning tunneling microscopy (STM) images from TiO2(110) surfaces. After annealing nearly perfect stoichiometric 1×1 surfaces to elevated temperatures in ultrahigh vacuum, randomly distributed oxygen vacancies are observed. The apparent shape of these defects provides strong evidence that the STM is imaging undercoordinated Ti atoms, as do first-principles pseudopotential calculations of the electronic states accessible to tunneling. We thus resolve a controversy as to whether STM imaging on this surface is dominated by geometric-structure or electronic effects.

  • Received 14 March 1996

DOI:https://doi.org/10.1103/PhysRevLett.77.1322

©1996 American Physical Society

Collections

This article appears in the following collection:

Scanning Probe Microscopy: From Sublime to Ubiquitous

This collection marks the 35th anniversary of scanning tunneling microscopy (STM) and the 30th anniversary of atomic force microscopy (AFM). These papers, all published in the Physical Review journals, highlight the positive impact that STM and AFM have had, and continue to have, on physical science research. The papers included in the collection have been made free to read.

Authors & Affiliations

Ulrike Diebold and J. F. Anderson

  • Department of Physics, Tulane University, New Orleans, Louisiana 70118

Kwok-On Ng and David Vanderbilt

  • Department of Physics and Astronomy and Laboratory for Surface Modification, Rutgers, The State University of New Jersey, Piscataway, New Jersey 08904

References

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Issue

Vol. 77, Iss. 7 — 12 August 1996

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