Abstract
We present a theoretical investigation of the origin of Raman-like and fluorescencelike (FL) features of resonant inelastic x-ray scattering (RIXS) spectra. Using a combination of local-density mean-field theory and a configuration interaction solver for Anderson impurity model, we calculate the -edge RIXS and x-ray absorption spectra of high-valence transition-metal oxides and . We analyze in detail the behavior of the FL feature and show how it is connected to the details of electronic and crystal structure. On the studied compounds we demonstrate how material details determine whether the electron-hole continuum can be excited in the -edge RIXS process.
- Received 13 March 2018
- Revised 18 July 2018
DOI:https://doi.org/10.1103/PhysRevLett.121.126403
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