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Structures and Dynamics of Glass-Forming Colloidal Liquids under Spherical Confinement

Bo Zhang and Xiang Cheng
Phys. Rev. Lett. 116, 098302 – Published 2 March 2016
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Abstract

Recent theories predict that when a supercooled liquid approaches the glass transition, particle clusters with a special “amorphous order” nucleate within the liquid, which lead to static correlations dictating the dramatic slowdown of liquid relaxation. The prediction, however, has yet to be verified in 3D experiments. Here, we design a colloidal system, where particles are confined inside spherical cavities with an amorphous layer of particles pinned at the boundary. Using this novel system, we capture the amorphous-order particle clusters and demonstrate the development of a static correlation. Moreover, by investigating the dynamics of spherically confined samples, we reveal a profound influence of the static correlation on the relaxation of colloidal liquids. In analogy to glass-forming liquids with randomly pinned particles, we propose a simple relation for the change of the configurational entropy of confined colloidal liquids, which quantitatively explains our experimental findings and illustrates a divergent static length scale during the colloidal glass transition.

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  • Received 24 August 2015

DOI:https://doi.org/10.1103/PhysRevLett.116.098302

© 2016 American Physical Society

Physics Subject Headings (PhySH)

  1. Physical Systems
Polymers & Soft Matter

Synopsis

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Order in Glasses

Published 2 March 2016

Correlated patterns of particles form in colloidal liquids as they approach the glass transition.

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Authors & Affiliations

Bo Zhang and Xiang Cheng*

  • Department of Chemical Engineering and Materials Science, University of Minnesota, Minneapolis, Minnesota 55455, USA

  • *xcheng@umn.edu

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Issue

Vol. 116, Iss. 9 — 4 March 2016

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