Abstract
Absolute transition frequencies of the transitions in were measured for the isotopes . The fine structure splitting of the state and its isotope dependence are extracted and compared to results of ab initio calculations using explicitly correlated basis functions, including relativistic and quantum electrodynamics effects at the order of and . Accuracy has been improved in both the theory and experiment by 2 orders of magnitude, and good agreement is observed. This represents one of the most accurate tests of quantum electrodynamics for many-electron systems, being insensitive to nuclear uncertainties.
- Received 10 March 2015
DOI:https://doi.org/10.1103/PhysRevLett.115.033002
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Published by the American Physical Society