Abstract
We introduce and characterize a first-order model for a generic class of colloidal particles that have a preferred spherical shape but can undergo deformations while always maintaining hard-body interactions. The model consists of hard spheres that can continuously change shape at fixed volume into prolate or oblate ellipsoids of revolution, subject to an energetic penalty. The severity of this penalty is specified by a single parameter that determines the flexibility of the particles. The deformable hard spheres crystallize at higher packing fractions than rigid hard spheres, have a narrower solid-fluid coexistence region and can reach high densities by a second transition to an orientationally ordered crystal.
- Received 16 April 2010
DOI:https://doi.org/10.1103/PhysRevLett.105.088305
© 2010 The American Physical Society
Synopsis
Shape shifting
Published 20 August 2010
The ease with which proteins in a colloid change shape is one factor limiting how well they crystallize.
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