Comment on “Spontaneous liquid-liquid phase separation of water”

David T. Limmer and David Chandler
Phys. Rev. E 91, 016301 – Published 23 January 2015

Abstract

Yagasaki et al. [Phys. Rev. E 89, 020301 (2014)] present results from a molecular dynamics trajectory illustrating coarsening of ice, which they interpret as evidence of transient coexistence between two distinct supercooled phases of liquid water. We point out that neither two distinct liquids nor criticality are demonstrated in this simulation study. Instead, the illustrated trajectory is consistent with coarsening behaviors analyzed and predicted in earlier work by others.

  • Received 21 July 2014

DOI:https://doi.org/10.1103/PhysRevE.91.016301

©2015 American Physical Society

Authors & Affiliations

David T. Limmer1,* and David Chandler2,†

  • 1Princeton Center for Theoretical Science, Princeton University, Princeton, New Jersey 08544, USA
  • 2Department of Chemistry, University of California, Berkeley, California 94720, USA

  • *Corresponding author: dlimmer@princeton.edu
  • Corresponding author: chandler@berkeley.edu

Comments & Replies

Reply to “Comment on ‘Spontaneous liquid-liquid phase separation of water’ ”

Takuma Yagasaki, Masakazu Matsumoto, and Hideki Tanaka
Phys. Rev. E 91, 016302 (2015)

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Original Article

Spontaneous liquid-liquid phase separation of water

Takuma Yagasaki, Masakazu Matsumoto, and Hideki Tanaka
Phys. Rev. E 89, 020301(R) (2014)

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Vol. 91, Iss. 1 — January 2015

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