Attenuation of excitation decay rate due to collective effect

We study a series of $N$ oscillators, each coupled to its nearest neighbors, and linearly to a phonon field through the oscillator's number operator. We show that the Hamiltonian of a pair of adjacent oscillators, or a dimer, within the series of oscillators can be transformed into a form in which they are collectively coupled to the phonon field as a composite unit. In the weak coupling and rotating-wave approximation, the system behaves effectively as the trilinear boson model in the one excitation subspace of the dimer subsystem. The reduced dynamics of the one excitation subspace of the dimer subsystem coupled weakly to a phonon bath is similar to that of a two-level system, with a metastable state against the vacuum. The decay constant of the subsystem is proportional to the dephasing rate of the individual oscillator in a phonon bath, attenuated by a factor that depends on site asymmetry, intersite coupling, and the resonance frequency between the transformed oscillator modes, or excitons. As a result of the collective effect, the excitation relaxation lifetime is prolonged over the dephasing lifetime of an individual oscillator coupled to the same bath.

Figure 1

$1/\alpha$ vs $\left|\eta \right|$ for a few $\theta$, with parameters ${\omega }_1-{\omega }_2=120{\mathrm{cm}}^{-1}$, $J_{12}=-96{\mathrm{cm}}^{-1}$ [31], and ${\lambda }_1=35{\mathrm{cm}}^{-1}$ [17]. Solid, long-dashed, short-dashed, dotted-dashed, and dotted lines represent $\theta =0$, $\pi /4$, $\pi /2$, $3\pi /4$, and $\pi$, respectively.