Abstract
We present a detailed numerical study of the elementary condensation events (avalanches) associated to the adsorption of in silica aerogels. We use a coarse-grained lattice-gas description and determine the nonequilibrium behavior of the adsorbed gas within a local mean-field analysis, neglecting thermal fluctuations and activated processes. We investigate the statistical properties of the avalanches, such as their number, size and shape along the adsorption isotherms as a function of gel porosity, temperature, and chemical potential. Our calculations predict the existence of a line of critical points in the temperature-porosity diagram where the avalanche size distribution displays a power-law behavior and the adsorption isotherms have a universal scaling form. The estimated critical exponents seem compatible with those of the field-driven random field Ising model at zero temperature.
7 More- Received 10 August 2005
DOI:https://doi.org/10.1103/PhysRevE.72.051506
©2005 American Physical Society