Evolution of the space-charge layer during electrochemical deposition with convection

Vincent Fleury, James Kaufman, and Brynn Hibbert
Phys. Rev. E 48, 3831 – Published 1 November 1993
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Abstract

We study the effect of convection on the concentration profiles in electrolytic cells during electrochemical deposition without a supporting electrolyte. We give theoretical evidence that convection decreases the size of the space charge on the cathodic side during fast electrochemical deposition. This effect may provide a limiting amplitude of the convective motion.

  • Received 15 June 1993

DOI:https://doi.org/10.1103/PhysRevE.48.3831

©1993 American Physical Society

Authors & Affiliations

Vincent Fleury

  • Ecole Polytechnique, Laboratoire de Physique de la Matiére Condensée, 91128 Palaiseau, France

James Kaufman

  • IBM Research Division, K34/803, Almaden Research Center, 850 Harry Road, San Jose, California 85120-6099

Brynn Hibbert

  • School of Chemistry, University of New South Wales, P.O. Box 1, Kensington, New South Wales, Australia

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Vol. 48, Iss. 5 — November 1993

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