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Possibility of Coupling to haloform molecules in intercalated C60

Erik Koch and Olle Gunnarsson
Phys. Rev. B 67, 161402(R) – Published 14 April 2003
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Abstract

For field-effect-doped fullerenes it was reported that the superconducting transition temperature Tc is markedly larger for C602CHX3 (X=Cl,Br) crystals, than for pure C60. As a possible mechanism it was proposed that there is not only coupling to the vibrational modes of the C60 molecule, but also to the modes of the intercalated molecules. We investigate the possiblity of such a coupling. We find that, assuming the ideal bulk structure of the intercalated crystal, both a coupling due to hybridization of the molecular levels, and a coupling via dipole moments should be very small.

  • Received 24 July 2002

DOI:https://doi.org/10.1103/PhysRevB.67.161402

©2003 American Physical Society

Authors & Affiliations

Erik Koch* and Olle Gunnarsson

  • Max-Planck Institut für Festkörperforschung, Heisenbergstraße 1, 70569 Stuttgart, Germany

  • *Electronic address: E.Koch@fkf.mpg.de

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Vol. 67, Iss. 16 — 15 April 2003

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