Abstract
We present a nuclear magnetic resonance (NMR) study of and two compounds that are related by electron-hole symmetry in the triply degenerate conduction band. In both systems, it is known that NMR spin-lattice relaxation rate measurements detect a gap in the electronic structure, most likely related to singlet-triplet excitations of the Jahn-Teller distorted (JTD) or However, the extended temperature range of the measurements presented here (10 K to 700 K) allows one to reveal deviations with respect to this general trend, both at high and low temperatures. Above room temperature, deviates from the activated law that one would expect from the presence of the gap and saturates. In the same temperature range, a lowering of symmetry is detected by the appearance of quadrupole effects on the spectra of In modifications of the spectra line shapes also indicate a structural modification. We discuss this high-temperature deviation in terms of a coupling between JTD and local symmetry. At low temperatures, tends to a constant value for both for and NMR. This indicates a residual metallic character, which emphasizes the proximity of metallic and insulting behaviors in alkali fullerides.
- Received 28 February 2002
DOI:https://doi.org/10.1103/PhysRevB.66.155122
©2002 American Physical Society