Abstract
The electronic structure of CoO is studied by resonant inelastic soft x-ray scattering spectroscopy using photon energies across the Co absorption edges. The different energy-loss structures in the Raman scattering spectra are identified as due to and charge-transfer excitations. For excitation energies close to the resonance, the spectral features are dominated by quartet-quartet and quartet-doublet transitions of the configuration. At excitation energies corresponding to the satellites in the Co x-ray-absorption spectrum of CoO, the emission features are instead dominated by charge-transfer transitions to the final state. The spectra are interpreted and discussed with the support of simulations within the single-impurity Anderson model with full multiplet effects which are found to yield consistent spectral functions to the experimental data.
- Received 23 November 2001
DOI:https://doi.org/10.1103/PhysRevB.65.205106
©2002 American Physical Society