Abstract
Polarized reflectance measurements have been made on two isostructural conducting compounds of bis(ethylenedithio)tetrathiafulvalene [BEDT-TTF or ET, ()]: β-(ET and β-(ETBr. The former is superconducting at ambient pressure with =5 K, whereas the latter retains normal-metal conductivity to low temperatures. The reflectance measurements, made at temperatures of approximately 30 and 300 K, spanned 80 (0.01 eV) through 33 000 (∼4 eV); they were made for polarization along the ET molecular stacking axis and transverse to it in the sheets or layers of ET molecules. Band-structure parameters determined from the plasmon frequencies imply that the anisotropy is rather low for organic conductors, with ≊0.22 eV and ≊0.09 eV for β-(ET; ≊0.18 eV and ≊0.07 eV for β-(ETBr. At 300 K, the spectra differ substantially from the expectations of simple one-electron models, suggesting that both electron-phonon and electron-electron interactions play important roles in the electronic structure of these materials. At low temperatures, the materials display basically metallic characteristics, yet deviate significantly from simple Drude-model behavior. At 30 K, no effect attributable to superconducting fluctuations could be observed.
- Received 17 December 1986
DOI:https://doi.org/10.1103/PhysRevB.35.9605
©1987 American Physical Society