Role of elastic interaction in the disordered-pyrite to ordered-pyrite phase transition in sodium superoxide

Gabor Kemeny and S. D. Mahanti
Phys. Rev. B 20, 2961 – Published 1 October 1979
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Abstract

We analyze the effect of indirect orientation-dependent elastic coupling between molecules, recently studied by Michel and Naudts in NaCN and KCN, on the disordered-pyrite to ordered-pyrite phase transition in sodium superoxide (NaO2). We find that the inclusion of this indirect interaction does not affect our earlier results on the order-disorder transition obtained by including only the direct interaction between the O2 molecules. We also discuss the interplay between direct and indirect interaction in the structural phase transitions seen in other alkali superoxides.

  • Received 4 June 1979

DOI:https://doi.org/10.1103/PhysRevB.20.2961

©1979 American Physical Society

Authors & Affiliations

Gabor Kemeny

  • Department of Biophysics, Michigan State University, East Lansing, Michigan 48824

S. D. Mahanti

  • Department of Physics, Michigan State University, East Lansing, Michigan 48824

Original Article

Physical mechanisms in the phase transitions of sodium superoxide

S. D. Mahanti and Gabor Kemeny
Phys. Rev. B 20, 2105 (1979)

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Vol. 20, Iss. 7 — 1 October 1979

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